[ 儕儕乕僗丗 2021.03 ]
撧椙彈巕戝妛 棟妛晹 壔妛椞堟
乮桳婡嬥懏丒嶖懱壔妛尋媶僌儖乕僾乯
拞搰棽峴丒拞慜壚撨巕丒扞悾抦柧

丂嬤擭丆愇桘傗愇扽傪拞怱偲偟偨壔愇扽慺帒尮偺屚妷傗擇巁壔扽慺攔弌偵傛傞抧媴壏抔壔側偳恖椶偑書偊傞抧媴婯柾偺栤戣傪攚宨偵丆怴戙懼僄僱儖僊乕偺奐敪偲偲傕偵娐嫬傗帒尮偵晧壸偺彮側偄娐嫬偵桪偟偄暔幙幮夛偺峔抸偑嫮偔媮傔傜傟偰偄傑偡丅摿偵丆壔愇扽慺帒尮偑桳尷偱偁傞偙偲傪峫偊傟偽丆拞挿婜揑偵偼丆懢梲岝丆晽椡側偳偺嵞惗壜擻側堦師僄僱儖僊乕傪棙梡偟偰敪揹傪峴偄丆悈慺傪擇師僄僱儖僊乕偲偟偰塣斃丒挋憼偟僆儞僒僀僩偱擱椏揹抮摍偵傛傝揹椡傗摦椡傪摼傞偲偄偆幮夛僔僗僥儉偺峔抸偑昁梫偱偁傞偲峫偊傜傟傑偡乮恾1乯丅壗偟傠悈慺偲巁慺偺斀墳偐傜偼悈偟偐攔弌偝傟傑偣傫丅

恾侾丏悈慺傪擇師僄僱儖僊乕偲偡傞幮夛僔僗僥儉乮彨棃梊應乯

丂偟偐偟丆悈慺偼忢壏忢埑偱婥懱偱偁傝丆巁慺偲偺斀墳惈傕崅偄偺偱丆埨慡偵塣斃丒挋憼偡傞偙偲偑擄偟偄偲偄偭偨寚揰傕偁傝傑偡丅偦偺夝寛嶔偲偟偰悈慺傪桳婡暘巕偵尒偐偗忋庢傝崬傒丆昁梫偵墳偠偰悈慺傪庢傝弌偡偙偲偑偱偒傞悈慺僉儍儕傾偵拲栚偑廤傑偭偰偍傝丆偦偺岓曗偺堦偮偵偼僊巁乮媋巁乯偑偁傝傑偡乮恾2乯丅僊巁偼扽慺悢偑侾偺暘巕検偑嵟傕彫偝側僇儖儃儞巁偱偁傝丆媋乮偁傝乯偐傜敪尒偝傟偨偺偱偦偺柤偑晅偗傜傟偰偄傑偡偑丆忢壏忢埑偱塼懱偱偁傝丆埨掕偵塣斃丒挋憼偑壜擻偱偡丅僊巁偺峔憿幃(HCO₂H)傪尒傟偽傢偐傞傛偆偵丆僊巁偼悈慺(H₂)偲擇巁壔扽慺(CO₂)傪懌偟崌傢偣傞偲崌惉偱偒丆媡偵僊巁傪暘夝偡傞偲悈慺偲擇巁壔扽慺偑惗惉偡傞傛偆偵巚偊傑偡丅幚嵺偼偦傟傎偳娙扨偱偼偁傝傑偣傫偑丆偁傞庬偺怗攠傪梡偄傞偲幚尰偱偒傑偡丅偩偐傜僊巁偑悈慺僉儍儕傾偲偟偰桳朷側偺偱偡丅偮傑傝丆怗攠傪梡偄偰悈慺傪僊巁偵曄姺偟悈慺偺戙傢傝偵僊巁偲偟偰挋憼丒塣斃偟丆昁梫偵墳偠偰僊巁傪暘夝偡傞偙偲偱悈慺傪惗惉偱偒傑偡丅偦偺偨傔丆悈慺偲擇巁壔扽慺偐傜僊巁傪惗惉偡傞斀墳乮悈慺挋憼乯偍傛傃丆僊巁傪暘夝偟悈慺傪惗惉偡傞斀墳乮悈慺惗惉乯傪岠棪揑偵恑峴偝偣傞怗攠斀墳奐敪偑惙傫偵峴傢傟偰偄傑偡丅偙傟傑偱偵抦傜傟偰偄傞怗攠偺懡偔偑丆婱嬥懏偱偁傞Ir, Rh, Ru傪梡偄傑偡偑崅壙偱偡丅偦偺偨傔埨壙偱偁傞Fe, Ni, Cu側偳傪怗攠偲偡傞斀墳奐敪偵婜懸偑帩偨傟偰偄傑偡丅偙偺嬥懏偺拞偱偼Fe傗Ni傪梡偄偨尋媶椺偑嵟嬤憹偊偰偒偨傕偺偺Cu傪怗攠偲偡傞斀墳偼傎偲傫偳抦傜傟偰偄傑偣傫偱偟偨丅

恾俀丏悈慺僉儍儕傾偲偟偰偺僊巁偺摿挜

丂傢傟傢傟偺尋媶幒偱偼丆崅壙側婱嬥懏怗攠偺戙懼偲側傞埨壙側嬥懏怗攠偵傛傞斀墳奐敪傪栚揑偲偟偰摵僸僪儕僪嶖懱偵娭偡傞尋媶傪峴偭偰偒傑偟偨丅嬥懏僀僆儞傪埨掕壔偡傞偺偵桪傟偨摿挜傪帩偮儕儞尨巕傪暋悢傕偮懡嵗儂僗僼傿儞攝埵巕傪梡偄傞偲條乆側嬥懏悢(Cu₂, Cu₃, Cu₄, Cu₆, Cu₈, Cu₉, Cu₁₆)傗懡嵤側嬥懏崪奿傪傕偮摵僸僪儕僪懡妀嶖懱偑崌惉偱偒傞偙偲傪柧傜偐偵偟偰偒傑偟偨乮恾3乯[1]-[8]丅摵僸僪儕僪嶖懱偲偼丆摵僀僆儞偵悈慺尨巕偑寢崌偟偨壔崌暔偱丆摵嶖懱傪怗攠偲梡偄偨斀墳偺怗攠妶惈庬偲偟偰峫偊傜傟偰偒傑偟偨偑丆斀墳惈偑崅偔晄埨掕側偨傔丆偙傟傑偱偵扨棧偝傟峔憿夝愅偝傟偨椺偼尷傜傟偰偄傑偟偨丅

恾俁丏傢傟傢傟偺尋媶幒偱崌惉偟偨摵僸僪儕僪懡妀嶖懱

丂崌惉偝傟偨摵僸僪儕僪嶖懱偺斀墳惈傪専摙偡傞拞偱丆岾塣偵傕悈慺偲擇巁壔扽慺偐傜僊巁傪惗惉偡傞怗攠Cu₈H₆乮恾3(a)乯[7]偲丆僊巁傪暘夝偟偰悈慺傪惗惉偡傞怗攠Cu₆H₂乮恾3(d)乯[4]傪尒弌偡偙偲偑偱偒傑偟偨丅偙傟傜偺怗攠妶惈偼偄偢傟偺応崌傕丆婱嬥懏怗攠偵斾傋傞偲掅偄傕偺偱偼偁傝傑偡偑丆柺敀偄偙偲偵條乆側専摙偺寢壥丆怗攠妶惈庬偼摵僀僆儞偑暋悢廤傑偭偨懡妀摵拞怱偺峔憿傪傕偮偙偲偑梊憐偝傟傑偟偨乮恾4乯丅偙傟傑偱偵曬崘偝傟偰偄傞懡偔偺怗攠斀墳偼扨妀嬥懏拞怱乮1屄偺嬥懏乯偱恑峴偟偰偄傑偡丅堦曽丆懡妀拞怱偱斀墳偑恑傓椺偼捒偟偔丆暋悢偺嬥懏偑彆偗崌偆偙偲偱1屄偺嬥懏偩偗偱偼幚尰偱偒側偄斀墳惈偺敪尰偑婜懸偝傟偰偄傑偡丅偙偺傛偆側岠壥傪堦斒偵乽嬥懏娫偺嫤摨岠壥乿偲屇傃丆怗攠斀墳奐敪偵偍偄偰拲栚傪廤傔偰偄傑偡丅崱夞尒弌偟偨曬崘椺偺彮側偄摵怗攠偵傛傞僊巁偺惗惉偍傛傃暘夝斀墳偼丆傑偝偵暋悢偺摵僀僆儞偑嫤椡偡傞偙偲偵傛傞嫤摨岠壥偺寢壥偱偁傞偲峫偊傜傟傑偡丅崱屻偼丆偝傜側傞斀墳惈偺岦忋偵岦偗偰尋媶傪峴偭偰偄偔偲嫟偵丆摵懡妀拞怱傪棙梡偟偨怴偟偄斀墳偺奐敪傕栚巜偟偰偄偔梊掕偱偡丅

恾係丏梊憐偝傟傞怗攠斀墳儊僇僯僘儉 (a) 僊巁偺惗惉斀墳丆(b)僊巁偺暘夝斀墳

傕偭偲徻偟偄偙偲偑抦傝偨偄恖偺偨傔偵

[1] K. Nakamae, B. Kure, T. Nakajima, U. Ura, T. Tanase, Chem. Asian J. 9, 3106-3110 (2014).

[2] K. Nakamae, M. Tanaka, B. Kure, T. Nakajima, Y. Ura, T. Tanase, Chem. Eur. J. 23, 9457-9461 (2017).

[3] T. Nakajima, Y. Kamiryo, K. Hachiken, K. Nakamae, Y. Ura, T. Tanase, Inorg. Chem. 57, 11005-11018 (2018).

[4] T. Nakajima, Y. Kamiryo, M. Kishimoto, K. Imai, K. Nakamae, Y. Ura, T. Tanase, J. Am. Chem. Soc. 141, 8732-8736 (2019).

[5] T. Nakajima, K. Nakamae, R. Hatano, K. Imai, M. Harada, Y. Ura, T. Tanase, Dalton Trans. 48 (2019).

[6] T. Tanase, R. Otaki, A. Okue, K. Nakamae, T. Nakajima, Eur. J. Inorg. Chem. (2019) 3993-4005.

[7] K. Nakamae, T. Nakajima, Y. Ura, Y. Kitagawa, T. Tanase, Angew. Chem. Int. Ed. 59, 2262-2267 (2020).

[8] T. Nakajima, K. Nakamae, Y. Ura, T. Tanase, Eur. J. Inorg. Chem. 23, 2211-2226 (2020).